학제간연구 | Interdisciplinary Studies in Gambling | 跨学科研究
- date : 2015-05-19 20:59|hit : 2199
-
- Article] Characterizing metal(loid) solubility in airborne PM10, PM2.5 and PM1 in Frankfurt, Germany using simulated lung fluids
-
DocNo of ILP: 6
Doc. Type: Article
Title: Characterizing metal(loid) solubility in airborne PM10, PM2.5 and PM1 in Frankfurt, Germany using simulated lung fluids
Authors: Wiseman, CLS; Zereini, F
Full Name of Authors: Wiseman, Clare L. S.; Zereini, Fathi
Keywords by Author: Airborne PM; Metal bioaccessibility; Metal solubility; Simulated lung fluids; Artificial lysosomal fluid; Gamble's solution
Keywords Plus: HUMAN ALVEOLAR MACROPHAGES; AIR-POLLUTION PARTICLE; PARTICULATE MATTER; IN-VITRO; TRANSITION-METALS; TRACE-ELEMENTS; URBAN; PALLADIUM; PLATINUM; EMISSIONS
Abstract: The purpose of this study is to assess the solubility of traffic-related metal(loid)s associated with airborne PM of human health concern, employing a physiologically-based extraction test with simulated lung fluids (artificial lysosomal fluid (ALF) and Gamble's solution). Airborne PM (PM10, PM2.5 and PM1) samples were collected in Frankfurt am Main, Germany, using a high volume sampler. Following extraction of the soluble metal(loid) fractions, sample filters were digested with a high pressure ashen Metal(loid) concentrations (As, Ce, Co, Cr, Cu, Mn, Ni, Pb, Sb, Ti and V) were determined in extracts and digests per ICP-Q-MS. All metal(loid)s occurred at detectable concentrations in the three airborne PM fractions. Copper was the most abundant element in mass terms, with mean concentrations of 105 and 53 ng/m(3) in PM10 and PM2.5, respectively. Many of the metal(loid)s were observed to be soluble in simulated lung fluids, with Cu, As, V and Sb demonstrating the highest overall mobility in airborne PM. For instance, all four elements associated with PM10 had a solubility of >80% in ALF (24 h). Clearly, solubility is strongly pH dependent, as reflected by the higher relative mobility of samples extracted with the acidic ALF. Given their demonstrated solubility, this study provides indirect evidence that a number of toxic metal(loid)s are likely to possess an enhanced pulmonary toxic potential upon their inhalation. The co-presence of many toxic elements of concern in airborne PM suggests an assessment of health risk must consider the possible interactive impacts of multi-element exposures. (C) 2014 Elsevier Ltd. All rights reserved.
Cate of OECD: Earth and related environmental sciences
Year of Publication: 2014
Business Area: other
Detail Business: medicine & science
Country: England
Study Area: Evaluation, risk
Name of Journal: ATMOSPHERIC ENVIRONMENT
Language: English
Country of Authors: [Wiseman, Clare L. S.] Univ Toronto, Sch Environm, Toronto, ON M5S 3E8, Canada; [Zereini, Fathi] JW Goethe Univ Frankfurt, Dept Environm Analyt Chem, Inst Atmospher & Environm Sci, Frankfurt, Germany
Press Adress: Wiseman, CLS (reprint author), Univ Toronto, Sch Environm, 33 Willcocks St,Suite 1016V, Toronto, ON M5S 3E8, Canada.
Email Address: clare.wiseman@utoronto.ca
Citaion:
Funding:
Lists of Citation: Alsenz H, 2009, ANAL BIOANAL CHEM, V395, P1919, DOI 10.1007/s00216-009-3143-8; Amatullah H, 2012, INHAL TOXICOL, V24, P161, DOI 10.3109/08958378.2011.650235; Araya J, 2002, AM J PHYSIOL-LUNG C, V283, pL849, DOI 10.1152/ajplung.00422.2001; Artelt S., 1999, ATMOS ENVIRON, V33, P3359; Aschner M, 2006, NEUROTOXICOLOGY, V27, P733, DOI 10.1016/j.neuro.2006.10.005; Barrett K., 2008, 122008 ETCACC; Becker S, 2005, ENVIRON HEALTH PERSP, V113, P1032, DOI 10.1289/ehp.7996; Becker S, 2003, EXP LUNG RES, V29, P29, DOI 10.1080/01902140390116535; Brook RD, 2010, CIRCULATION, V121, P2331, DOI 10.1161/CIR.0b013e3181dbece1; Burnett RT, 1999, ARCH ENVIRON HEALTH, V54, P130; Carter JD, 1997, TOXICOL APPL PHARM, V146, P180, DOI 10.1006/taap.1997.8254; COLLIER CG, 1992, ENVIRON HEALTH PERSP, V97, P109, DOI 10.2307/3431337; Colombo C, 2008, ECOTOX ENVIRON SAFE, V71, P722, DOI 10.1016/j.ecoenv.2007.11.011; Costa DL, 1997, ENVIRON HEALTH PERSP, V105, P1053, DOI 10.2307/3433509; DOCKERY DW, 1993, NEW ENGL J MED, V329, P1753, DOI 10.1056/NEJM199312093292401; Falciani R, 2000, J ANAL ATOM SPECTROM, V15, P561, DOI 10.1039/b000742k; Forti E, 2011, TOXICOL IN VITRO, V25, P454, DOI 10.1016/j.tiv.2010.11.013; Golwer Arthur, 1998, Geologisches Jahrbuch Hessen, V126, P47; Health Effects Institute, 2001, HEI COMMUNICATION, V9; HILDEMANN LM, 1991, ENVIRON SCI TECHNOL, V25, P744, DOI 10.1021/es00016a021; IARC, 1987, MON EV CARC RISK S7, P100; Iavicoli I., 2011, URBAN AIRBORNE PARTI, P145; Klumpp A., 2011, URBAN AIRBORNE PARTI, P145; Kupiainen KJ, 2011, ATMOS ENVIRON, V45, P4141, DOI 10.1016/j.atmosenv.2011.05.027; Lin WS, 2006, INT J TOXICOL, V25, P451, DOI 10.1080/10915810600959543; McNeilly JD, 2004, TOXICOL APPL PHARM, V196, P95, DOI 10.1016/j.taap.2003.11.021; Messerschmidt J, 2000, ANALYST, V125, P397, DOI 10.1039/b000471p; Midander K, 2007, ENVIRON POLLUT, V145, P51, DOI 10.1016/j.envpol.2006.03.041; Mugica-Alvarez V, 2012, ATMOS ENVIRON, V49, P284, DOI 10.1016/j.atmosenv.2011.11.038; Mukhtar A, 2013, ANAL CHIM ACTA, V774, P11, DOI 10.1016/j.aca.2013.02.008; Puls C, 2012, ATMOS ENVIRON, V55, P213, DOI 10.1016/j.atmosenv.2012.03.023; Querol X, 2007, ATMOS ENVIRON, V41, P7219, DOI 10.1016/j.atmosenv.2007.05.022; Roig N, 2013, SCI TOTAL ENVIRON, V443, P791, DOI 10.1016/j.scitotenv.2012.11.022; Root RA, 2000, ENVIRON HEALTH PERSP, V108, P937, DOI 10.1289/ehp.00108937; Sternbeck J, 2002, ATMOS ENVIRON, V36, P4735, DOI 10.1016/S1352-2310(02)00561-7; Stopford W, 2003, J ENVIRON MONITOR, V5, P675, DOI 10.1039/b302257a; von Schneidemesser E., 2010, PAKISTAN SCI TOTAL E, V408, P1640; WANG CF, 1995, ANALYST, V120, P1681, DOI 10.1039/an9952001681; Wang DB, 2013, ATMOS ENVIRON, V77, P301, DOI 10.1016/j.atmosenv.2013.05.031; Wiseman CLS, 2013, SCI TOTAL ENVIRON, V442, P86, DOI 10.1016/j.scitotenv.2012.10.051; Zereini F, 2012, SCI TOTAL ENVIRON, V416, P261, DOI 10.1016/j.scitotenv.2011.11.070; Zereini F, 2012, ENVIRON SCI TECHNOL, V46, P10326, DOI 10.1021/es3020887; Zereini F., 2010, KONZENTRATIIONEN RAU, P128; Zereini F, 2005, ENVIRON SCI TECHNOL, V39, P2983, DOI 10.1021/es040040t
Number of Citaion: 44
Publication: PERGAMON-ELSEVIER SCIENCE LTD
City of Publication: OXFORD
Address of Publication: THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
ISSN: 1352-2310
29-Character Source Abbreviation: ATMOS ENVIRON
ISO Source Abbreviation: Atmos. Environ.
Volume: 89
Version:
Start of File: 282
End of File: 289
DOI: 10.1016/j.atmosenv.2014.02.055
Number of Pages: 8
Web of Science Category: Environmental Sciences; Meteorology & Atmospheric Sciences
Subject Category: Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences
Document Delivery Number: AH1IT
Unique Article Identifier: WOS:000335874500031
:
Ref: Web of Science, www.wokinfo.com
- reply : 0
-
- list
-
- prev